Standing
| Team | Pld. | W | D | L | Goals | Pts. | Qualification |
| Ukraine | 8 | 6 | 2 | 0 | 17-4 | 20 | UEFA Euro 2020 |
| Portugal | 8 | 5 | 2 | 1 | 22-6 | 17 | UEFA Euro 2020 |
| Serbia | 8 | 4 | 2 | 2 | 17-17 | 14 | |
| Luxembourg | 8 | 1 | 1 | 6 | 5-16 | 5 | |
| Lithuania | 8 | 0 | 1 | 7 | 5-25 | 1 |
Fixture
| Date | Host Team | Score | Away Team |
| 22-03-2019 | Luxembourg | 2-1 Leandro Barreiro Martins, Gerson Rodrigues / Fedor Cernych | Lithuania |
| 22-03-2019 | Portugal | 0-0 | Ukraine |
| 25-03-2019 | Luxembourg | 1-2 David Turpel / Viktor Tsygankov, Gerson Rodrigues (og) | Ukraine |
| 25-03-2019 | Portugal | 1-1 William Carvalho / Dusan Tadiç | Serbia |
| 07-06-2019 | Lithuania | 1-1 Arvydas Novikovas / Gerson Rodrigues | Luxembourg |
| 07-06-2019 | Ukraine | 5-0 Viktor Tsygankov (2), Yevgen Konoplyanka (2), Roman Yaremchuk | Serbia |
| 10-06-2019 | Serbia | 4-1 Aleksandar Mitrovic (2), Luka Jovic, Adem Ljajic / Arvydas Novikovas | Lithuania |
| 10-06-2019 | Ukraine | 1-0 Roman Yaremchuk | Luxembourg |
| 07-09-2019 | Lithuania | 0-3 Oleksandr Zinchenko, Marlos, Ruslan Malinovskiy | Ukraine |
| 07-09-2019 | Serbia | 2-4 Nikola Milenkovic, Stefan Mitrovic / Cristiano Ronaldo, Adrien Silva William, Carvalho, Goncalo Guedes | Portugal |
| 10-09-2019 | Lithuania | 1-5 Vytautas Andriuskevicius / Cristiano Ronaldo (4), William Carvalho | Portugal |
| 10-09-2019 | Luxembourg | 1-3 David Turpel / Stefan Mitrovic (2), Nemanja Radonjic | Serbia |
| 11-10-2019 | Portugal | 3-0 Adrien Silva, Cristiano Ronaldo, Goncalo Guedes | Luxembourg |
| 11-10-2019 | Ukraine | 2-0 Ruslan Malinovskiy (2) | Lithuania |
| 14-10-2019 | Ukraine | 2-1 Roman Yaremchuk, Andriy Yarmolenko / Cristiano Ronaldo | Portugal |
| 14-10-2019 | Lithuania | 1-2 Donatas Kazlauskas / Aleksandar Mitrovic (2) | Serbia |
| 15-11-2019 | Portugal | 6-0 Cristiano Ronaldo (3), Pizzi, Goncalo Paciencia, Adrien Silva | Lithuania |
| 15-11-2019 | Serbia | 3-2 Aleksandar Mitrovic (2), Nemanja Radonjic / Ralph Schon, David Turpel | Luxembourg |
| 17-11-2019 | Luxembourg | 0-2 Manuel Fernandes, Cristiano Ronaldo | Portugal |
| 17-11-2019 | Serbia | 2-2 Dusan Tadic, Aleksandar Mitrovic / Roman Yaremchuk, Artem Besedin | Ukraine |