Round 4
| Date | Host Team | Score | Away Team |
| 24-10-2019 | Anadolu Efes | 76-60 | Real Madrid |
| 24-10-2019 | Crvena Zvezda mts Belgrade | 65-73 | FC Barcelona |
| 24-10-2019 | Zenit St.Petersburg | 79-89 | Panathinaikos OPAP Athens |
| 24-10-2019 | Maccabi FOX Tel Aviv | 76-63 | Valencia Basket |
| 24-10-2019 | FC Bayern Münich | 74-87 | Khimki Moscow Region |
| 25-10-2019 | Zalgiris Kaunas | 70-56 | LDLC Asvel Villeurbanne |
| 25-10-2019 | AX Armani Exchange Milano | 87-74 | F.Bahçe BEKO |
| 25-10-2019 | Kirolbet Baskonia Vitoria-Gasteiz | 82-66 | Olympiacos |
| 25-10-2019 | Alba Berlin | 66-82 | CSKA Moscow |