Participating Teams

Rank	Country	Team(s)	Outcome (Qualified to)
11	Austria	SK Zadruga Aich	—
12	Serbia	Vojvodina NS Seme Novi Sad	—
14	Finland	Vammalan Lentopallo Sastmala	—
16	Montenegro	OK Budva	—
18	Belarus	VC Shakhtior Soligorsk	—
20	Romania	CS Arcada Galați	—
25	Bosnia and Herzegovina	OK Mladost Brcko	—
25	Croatia	Mladost Zagreb	—
31	England	IBB Polonia London	—
50	Portugal	SL Benfica Lisboa	—

First round

Team 1	Agg.	Team 2	1st leg	2nd leg
Mladost Zagreb	6–0	IBB Polonia London	3–0 (25-11, 25-17, 25-14)	3–0 (25-9, 25-12, 25-22)
OK Mladost Brcko	0–6	SL Benfica Lisboa	0–3 (22-25, 17-25, 21-25)	0–3 (18-25, 30-32, 15-28)

Second round

Team 1	Agg.	Team 2	1st leg	2nd leg
HAOK Mladost Zagreb	3–3	SK Posojilnica	3–1 (22-25, 25-18, 25-21, 25-14)	1–3 (28-26, 18-25, 26-28, 23-25) Golden Set: 15-9
SL Benfica Lisboa	6–0	OK Budva	3–0 (25-15, 25-17, 25-18)	3–1 (15-25, 25-21, 25-22, 27-25)
VC Shakhtior Soligorsk	6–0	Vammalan Lentopallo Sastmala	3–0 (29-27, 25-22, 25-13)	3–0 (25-22, 25-22, 25-21)
CS Arcada Galați	3–3	Vojvodina NS Seme Novi Sad	3–0 (25-23, 25-17, 25-21)	1–3 (20-25, 25-21, 21-25, 22-25) Golden Set: 11-15

Third round

Team 1	Agg.	Team 2	1st leg	2nd leg
SL Benfica Lisboa	6–0	HAOK Mladost Zagreb	3–0 (25-22, 25-20, 25-22)	3–1 (25-20, 25-19, 20-25, 25-21))
Vojvodina NS Seme Novi Sad	6–0	VC Shakhtior Soligorsk	3–0 (25-21, 25-18, 25-18)	3–0 (25-23, 25-18, 25-22)

2019–20 CEV Champions League